Hello @alosarjos, this is functionally a duplicate of #10442. Closing as a duplicate.
It looks like the Guide Button Chord settings are the culprit here. Adjusting these should prevent the dialog from appearing unexpectedly.
I’ve detailed the fix in this comment:
https://github.com/ValveSoftware/steam-for-linux/issues/10442#issuecomment-4148325257
Your system information
Please describe your issue in as much detail as possible:
Only when Steam is running, if using a DualSense PS5 Controller (In my case through Bluetooth), if I press the PlayStation button and move the left stick in any direction of Up, Right, Down, Left (Non diagonal), it triggers the remote desktop functionality of Gnome to share the screen
Steps for reproducing this issue:
If Steam is closed, it doesn't trigger anything, so looks like a Steam issue?