I'm currently experiencing this issue in Ubuntu 16.04. I've tested CS:GO and Portal 2, and both games perform significantly worse in BPM compared to desktop mode.
In Portal 2, disabling Multicore Rendering improved performance quite a bit, but doing the same in CS:GO didn't seem to improve it at all.
In Portal 2, I've noticed a bug that I suspect has something to do with this issue. When navigating the Options menu and a tooltip appears, pressing A on the Steam Controller doesn't make the tooltip go away, even though it should. I've found that in order to fix this, I have to use my mouse and click once anywhere on the screen. It's as if the game's window was no longer focused.
Nothing extracted yet.
I've noticed when launching a game from Big Picture Mode that after about 5 to 10 minutes of game play the frame rate drops to exceedingly low levels. That happened with both Portal 2 and Metro Last Light.
Processor Information:
Vendor: GenuineIntel
CPU Family: 0x6
CPU Model: 0x17
CPU Stepping: 0xa
CPU Type: 0x0
Speed: 3599 Mhz
4 logical processors
4 physical processors
HyperThreading: Unsupported
FCMOV: Supported
SSE2: Supported
SSE3: Supported
SSSE3: Supported
SSE4a: Unsupported
SSE41: Supported
SSE42: Unsupported
Network Information:
Network Speed:
Operating System Version:
Linux Mint 16 Petra (64 bit)
Kernel Name: Linux
Kernel Version: 3.11.0-12-generic
X Server Vendor: The X.Org Foundation
X Server Release: 11405000
X Window Manager: Marco
Steam Runtime Version: steam-runtime-release_2014-02-05
Video Card:
Driver: NVIDIA Corporation GeForce GTX 560/PCIe/SSE2
Sound card:
Audio device: Realtek ALC889A
Memory:
RAM: 3952 Mb
Miscellaneous:
UI Language: English
LANG: en_US.UTF-8
Microphone: Not set
Total Hard Disk Space Available: 55936 Mb
Largest Free Hard Disk Block: 21679 Mb